Question 31 of 513
You are provided with five gas jars containing SO2, CO2, H2, CO and NO respectively. Select a test from A to E which will identify ANY ONE of the gases completely
- A. pass each gas into lime water
- B. pass each gas into water and test with litmus paper
- C. pass each gas into concentrated sulphuric acid
- D. expose each gas to atmospheric air
Correct Answer:
A
Explanation
### Correct Option: A. Pass each gas into lime water
### Detailed Explanation:
To identify gases, we often use specific tests that can produce observable changes or reactions. In this case, we have five gases: sulfur dioxide (SO₂), carbon dioxide (CO₂), hydrogen (H₂), carbon monoxide (CO), and nitrogen monoxide (NO). Let's analyze the options provided to see which one can effectively identify at least one of these gases.
#### Option A: Pass each gas into lime water
- **Lime water** is a dilute solution of calcium hydroxide (Ca(OH)₂). When carbon dioxide (CO₂) is bubbled through lime water, it reacts to form calcium carbonate (CaCO₃), which is insoluble and causes the solution to turn cloudy. The reaction is as follows:
\[
\text{CO}_2 + \text{Ca(OH)}_2 \rightarrow \text{CaCO}_3 \downarrow + \text{H}_2\text{O}
\]
- **Sulfur dioxide (SO₂)** can also react with lime water, but it produces calcium sulfite (CaSO₃), which does not cause cloudiness. Therefore, while lime water can identify CO₂ effectively, it does not provide a clear indication for SO₂.
- **Conclusion**: This test can definitively identify CO₂, making option A a valid choice for identifying at least one gas.
#### Option B: Pass each gas into water and test with litmus paper
- This method involves dissolving the gases in water and then testing the resulting solution with litmus paper to determine if it is acidic or basic.
- **CO₂** dissolves in water to form carbonic acid (H₂CO₃), which is weakly acidic and would turn blue litmus paper red.
- **SO₂** also dissolves in water to form sulfurous acid (H₂SO₃), which is acidic and would similarly turn blue litmus paper red.
- **H₂** is neutral and would not change the color of litmus paper.
- **CO** is also neutral and would not affect litmus paper.
- **NO** can form nitric acid (HNO₃) in water, which is acidic and would turn blue litmus paper red.
- **Conclusion**: While this method can identify CO₂, SO₂, and NO, it does not provide a clear distinction between them, making it less effective than option A.
#### Option C: Pass each gas into concentrated sulfuric acid
- Concentrated sulfuric acid (H₂SO₄) is a strong dehydrating agent and can react with some gases.
- **H₂** would not react significantly with sulfuric acid.
- **CO** does not react with sulfuric acid.
- **NO** can react to form nitrogen dioxide (NO₂), but this does not provide a clear identification.
- **SO₂** can react with sulfuric acid, but again, this does not yield a clear identification.
- **CO₂** does not react with concentrated sulfuric acid in a way that would provide a clear identification.
- **Conclusion**: This option is not effective for identifying any of the gases clearly.
#### Option D: Expose each gas to atmospheric air
- Exposing gases to atmospheric air does not provide a specific test for identification.
- **H₂** is flammable and would burn in air, but this does not identify it specifically.
- **CO** is also flammable and can produce carbon dioxide when burned, but again, this does not provide a clear identification.
- **NO** can react with oxygen to form NO₂, but this does not help in identifying it.
- **SO₂** and **CO₂** do not have distinctive reactions with air that would allow for identification.
- **Conclusion**: This option is not effective for identifying any of the gases.
### Summary of Why Option A is Correct:
- Option A provides a clear and definitive test for identifying carbon dioxide (CO₂) through the formation of a cloudy precipitate in lime water.
- Other options either do not provide a clear identification or can identify multiple gases without distinguishing between them.
### Revision Summary:
- **Lime water test**: Identifies CO₂ by turning cloudy.
- **Litmus paper test**: Can indicate acidity but does not distinguish between gases effectively.
- **Concentrated sulfuric acid**: Does not provide clear identification for any of the gases.
- **Exposure to air**: Does not yield specific identification for the gases.
By understanding these tests and their reactions, you can effectively identify gases in a laboratory setting.