Question 37 of 513
Which of the following is an example of a condensation reaction?
- A. Acetic acid + ethanol → ethyl acetate + water
- B. Ethylene + chlorine → dichloroethane
- C. Chlorine + water → hydrochloric acid + oxygen
- D. Nitrogen + oxygen → nitrogen oxide
Correct Answer:
A
Explanation
### Correct Option: A. Acetic acid + ethanol → ethyl acetate + water
#### Explanation of Why Option A is Correct:
A condensation reaction is a type of chemical reaction where two molecules combine to form a larger molecule, with the simultaneous loss of a small molecule, often water. In the case of option A, acetic acid (CH₃COOH) reacts with ethanol (C₂H₅OH) to form ethyl acetate (CH₃COOC₂H₅) and water (H₂O).
**Step-by-Step Breakdown:**
1. **Reactants**: The reactants are acetic acid and ethanol.
- Acetic acid has a carboxylic acid functional group (-COOH).
- Ethanol has a hydroxyl group (-OH).
2. **Reaction Mechanism**:
- The hydroxyl group (-OH) from acetic acid and a hydrogen atom (H) from the hydroxyl group of ethanol combine to form water (H₂O).
- The remaining parts of the molecules (the acyl group from acetic acid and the ethyl group from ethanol) bond together to form ethyl acetate.
3. **Products**: The products of this reaction are ethyl acetate and water.
- Ethyl acetate is an ester, which is formed through the condensation of an alcohol and a carboxylic acid.
4. **Overall Reaction**:
\[
\text{CH}_3\text{COOH} + \text{C}_2\text{H}_5\text{OH} \rightarrow \text{CH}_3\text{COOC}_2\text{H}_5 + \text{H}_2\text{O}
\]
This reaction exemplifies a condensation reaction because it involves the formation of a new bond (the ester bond) and the release of water.
#### Why the Other Options are Incorrect:
- **Option B: Ethylene + chlorine → dichloroethane**
- This reaction is an example of an addition reaction, not a condensation reaction. In this case, ethylene (C₂H₄) reacts with chlorine (Cl₂) to form dichloroethane (C₂H₄Cl₂) without the loss of any small molecule. The double bond in ethylene is broken, and chlorine atoms are added across the double bond.
- **Option C: Chlorine + water → hydrochloric acid + oxygen**
- This reaction is a redox reaction and not a condensation reaction. Chlorine reacts with water to produce hydrochloric acid (HCl) and oxygen (O₂). There is no formation of a larger molecule from smaller ones with the loss of a small molecule.
- **Option D: Nitrogen + oxygen → nitrogen oxide**
- This reaction is a combination reaction, where nitrogen (N₂) and oxygen (O₂) combine to form nitrogen oxides (NO or NO₂). Similar to option C, this does not involve the loss of a small molecule and does not fit the definition of a condensation reaction.
### Summary:
- **Condensation Reaction**: Involves the combination of two molecules with the loss of a small molecule (often water).
- **Correct Example**: Acetic acid and ethanol form ethyl acetate and water, demonstrating a condensation reaction.
- **Other Options**:
- Option B is an addition reaction.
- Option C is a redox reaction.
- Option D is a combination reaction.
### Revision Summary:
- A condensation reaction produces a larger molecule and releases a small molecule (like water).
- Acetic acid + ethanol → ethyl acetate + water is a classic example of a condensation reaction.
- Addition, redox, and combination reactions do not fit the criteria for condensation reactions.