Question 25 of 513
Consider the following equation H2O + 2Fe2+ + Cl2 ↔ 2Fe3+ + 2Cl- + H2O. Which behaves as an oxidizing agent?
- A. Fe2+
- B. Cl2
- C. Fe3+
- D. Cl-
Correct Answer:
B
Explanation
The correct option is **B. Cl2**.
### Detailed Explanation:
1. **Understanding Oxidizing Agents**:
- An oxidizing agent is a substance that gains electrons in a chemical reaction and, in the process, causes another substance to be oxidized. This means that the oxidizing agent itself is reduced (it undergoes a decrease in oxidation state).
2. **Analyzing the Reaction**:
- The given reaction is:
\[
\text{H}_2\text{O} + 2\text{Fe}^{2+} + \text{Cl}_2 \rightleftharpoons 2\text{Fe}^{3+} + 2\text{Cl}^- + \text{H}_2\text{O}
\]
- In this reaction, we need to identify which species is being reduced (gaining electrons) and which is being oxidized (losing electrons).
3. **Identifying Oxidation States**:
- **Fe²⁺ to Fe³⁺**: The iron ion (Fe²⁺) is oxidized to Fe³⁺. This means it loses an electron:
\[
\text{Fe}^{2+} \rightarrow \text{Fe}^{3+} + e^-
\]
- **Cl₂ to Cl⁻**: The chlorine molecule (Cl₂) is reduced to chloride ions (Cl⁻). This means it gains electrons:
\[
\text{Cl}_2 + 2e^- \rightarrow 2\text{Cl}^-
\]
4. **Determining the Oxidizing Agent**:
- Since Cl₂ is gaining electrons and being reduced to Cl⁻, it is acting as the oxidizing agent in this reaction. It facilitates the oxidation of Fe²⁺ to Fe³⁺ by accepting electrons.
### Why the Other Options are Incorrect:
- **A. Fe²⁺**:
- Fe²⁺ is being oxidized to Fe³⁺, meaning it is losing electrons. Therefore, it cannot be an oxidizing agent; it is a reducing agent instead.
- **C. Fe³⁺**:
- Fe³⁺ is the product of the oxidation of Fe²⁺. It does not participate in the reduction process and thus cannot be an oxidizing agent.
- **D. Cl⁻**:
- Cl⁻ is the product of the reduction of Cl₂. Since it has already gained electrons, it cannot act as an oxidizing agent; it is a reduced form of chlorine.
### Summary of Key Points:
- An oxidizing agent gains electrons and is reduced in a chemical reaction.
- In the reaction provided, Cl₂ is reduced to Cl⁻, making it the oxidizing agent.
- Fe²⁺ is oxidized to Fe³⁺, acting as a reducing agent.
- Understanding oxidation states is crucial for identifying oxidizing and reducing agents in redox reactions.
### Revision Summary:
- **Oxidizing agents gain electrons and are reduced.**
- **Cl₂ is reduced to Cl⁻, making it the oxidizing agent in the reaction.**
- **Fe²⁺ is oxidized to Fe³⁺, acting as a reducing agent.**
- **Always check oxidation states to determine the roles of different species in redox reactions.**