Question 327 of 513
Which of the following statements correctly describes the behavior of acids and bases in aqueous solutions?
- Acids donate hydroxide ions (OH⁻) while bases donate protons (H⁺).
- Acids donate protons (H⁺) while bases accept protons (H⁺).
- Acids and bases both donate hydroxide ions (OH⁻).
- Acids accept protons (H⁺) while bases donate hydroxide ions (OH⁻).
Correct Answer:
B
Explanation
The correct option is **B. Acids donate protons (H⁺) while bases accept protons (H⁺).**
### Detailed Explanation:
1. **Understanding Acids and Bases:**
- The behavior of acids and bases in aqueous solutions is primarily described by the Brønsted-Lowry theory. According to this theory:
- **Acids** are substances that can donate protons (H⁺ ions).
- **Bases** are substances that can accept protons (H⁺ ions).
2. **Why Option B is Correct:**
- When an acid dissolves in water, it releases H⁺ ions into the solution. For example, hydrochloric acid (HCl) dissociates in water as follows:
\[
\text{HCl} \rightarrow \text{H}^+ + \text{Cl}^-
\]
- In this reaction, HCl donates a proton (H⁺), which is characteristic of acids.
- Conversely, when a base is present in the solution, it can accept these protons. For instance, ammonia (NH₃) can accept a proton to form ammonium (NH₄⁺):
\[
\text{NH}_3 + \text{H}^+ \rightarrow \text{NH}_4^+
\]
- This demonstrates that bases accept protons, aligning perfectly with the definition provided in option B.
3. **Why the Other Options are Incorrect:**
- **Option A: Acids donate hydroxide ions (OH⁻) while bases donate protons (H⁺).**
- This statement is incorrect because acids do not donate hydroxide ions; they donate protons (H⁺). Hydroxide ions (OH⁻) are typically associated with bases, not acids.
- **Option C: Acids and bases both donate hydroxide ions (OH⁻).**
- This is incorrect because acids do not donate hydroxide ions. Instead, they release protons (H⁺). Bases, on the other hand, can produce hydroxide ions in solution (e.g., NaOH dissociates to give Na⁺ and OH⁻).
- **Option D: Acids accept protons (H⁺) while bases donate hydroxide ions (OH⁻).**
- This statement is also incorrect. Acids do not accept protons; they donate them. While bases can produce hydroxide ions, they are defined as proton acceptors, not as donors of hydroxide ions.
### Summary of Key Concepts:
- **Acids**: Substances that donate protons (H⁺) in aqueous solutions.
- **Bases**: Substances that accept protons (H⁺) in aqueous solutions.
- The Brønsted-Lowry theory is fundamental in understanding acid-base behavior.
- Misunderstanding the definitions can lead to confusion about the nature of acids and bases.
### Revision Summary:
- Acids donate protons (H⁺), while bases accept protons (H⁺).
- Hydroxide ions (OH⁻) are associated with bases, not acids.
- The Brønsted-Lowry theory is key to understanding acid-base reactions.
- Always remember the definitions to avoid confusion in exam scenarios.