Question 281 of 513
Which of the following elements has the highest electronegativity according to the Pauling scale?
- Sodium (Na)
- Chlorine (Cl)
- Fluorine (F)
- Oxygen (O)
Correct Answer:
C
Explanation
**Correct Option: C. Fluorine (F)**
### Explanation of the Correct Answer
Electronegativity is a measure of an atom's ability to attract and hold onto electrons when it is part of a compound. The Pauling scale is one of the most commonly used scales to quantify electronegativity, and it assigns values to elements based on their ability to attract electrons in a chemical bond.
1. **Understanding Electronegativity**:
- Electronegativity increases across a period (from left to right on the periodic table) because the number of protons in the nucleus increases, which enhances the positive charge and the ability to attract electrons.
- Electronegativity decreases down a group (from top to bottom) because the additional electron shells increase the distance between the nucleus and the valence electrons, reducing the nucleus's pull on the bonding electrons.
2. **Position of Elements in the Periodic Table**:
- **Sodium (Na)**: Located in Group 1 (alkali metals), sodium has a low electronegativity of about 0.93. Alkali metals tend to lose electrons easily rather than attract them.
- **Chlorine (Cl)**: Found in Group 17 (halogens), chlorine has a higher electronegativity of about 3.16. It is quite effective at attracting electrons but is not the highest.
- **Oxygen (O)**: Located in Group 16, oxygen has an electronegativity of about 3.44. It is very electronegative but still lower than fluorine.
- **Fluorine (F)**: Positioned in Group 17, fluorine has the highest electronegativity value of 4.0 on the Pauling scale. This is due to its small atomic size and high effective nuclear charge, which allows it to attract electrons very strongly.
3. **Comparison of Electronegativity Values**:
- **Fluorine (F)**: 4.0
- **Oxygen (O)**: 3.44
- **Chlorine (Cl)**: 3.16
- **Sodium (Na)**: 0.93
From these values, it is clear that fluorine has the highest electronegativity.
### Explanation of Why Other Options Are Incorrect
- **A. Sodium (Na)**: Sodium is an alkali metal with a very low electronegativity. It tends to lose its single valence electron rather than attract electrons, making it the least electronegative among the options.
- **B. Chlorine (Cl)**: While chlorine is quite electronegative, it is not as electronegative as fluorine. Chlorine's ability to attract electrons is strong, but it is outmatched by fluorine's superior ability due to its smaller atomic radius and higher effective nuclear charge.
- **D. Oxygen (O)**: Oxygen is indeed very electronegative, but it still does not reach the level of fluorine. The difference in electronegativity between oxygen and fluorine is significant enough to place fluorine at the top of the scale.
### Summary of Key Points
- **Electronegativity** measures an atom's ability to attract electrons in a bond.
- **Fluorine (F)** has the highest electronegativity on the Pauling scale (4.0).
- **Oxygen (O)** and **Chlorine (Cl)** are less electronegative than fluorine, with values of 3.44 and 3.16, respectively.
- **Sodium (Na)** has the lowest electronegativity (0.93) among the options provided.
This understanding of electronegativity is crucial for predicting how different elements will interact in chemical reactions, especially in the formation of ionic and covalent bonds.