Question 224 of 513
When CuSO\(_{4(aq)}\) is added to Pb(NO\(_{3}\))\(_{2(aq)}\)--------
- A. there would be no visible change
- B. a blue precipitate would be formed
- C. the resulting solution would become colourless
- D. a white precipitate would be formed
Correct Answer:
D
Explanation
To understand the reaction between copper(II) sulfate (CuSO\(_4\)) and lead(II) nitrate (Pb(NO\(_3\))\(_2\)), let's break down the components and the expected outcomes step by step.
### Step 1: Identify the Reactants
- **Copper(II) sulfate (CuSO\(_4\))**: This is a blue ionic compound that dissociates in water to form Cu\(^{2+}\) ions and SO\(_4^{2-}\) ions.
- **Lead(II) nitrate (Pb(NO\(_3\))\(_2\))**: This is a colorless ionic compound that dissociates in water to form Pb\(^{2+}\) ions and NO\(_3^{-}\) ions.
### Step 2: Write the Dissociation Equations
When these compounds are dissolved in water, they dissociate as follows:
- CuSO\(_4\) (aq) → Cu\(^{2+}\) (aq) + SO\(_4^{2-}\) (aq)
- Pb(NO\(_3\))\(_2\) (aq) → Pb\(^{2+}\) (aq) + 2 NO\(_3^{-}\) (aq)
### Step 3: Predict the Reaction
When these two solutions are mixed, we need to consider the possible reactions between the ions present:
- Cu\(^{2+}\) (aq) + Pb\(^{2+}\) (aq) + SO\(_4^{2-}\) (aq) + 2 NO\(_3^{-}\) (aq)
In this case, we are looking for a possible precipitation reaction. The key is to identify if any of the combinations of ions will form an insoluble compound.
### Step 4: Identify Possible Products
The potential products from the ions in solution are:
1. CuSO\(_4\) (remains in solution)
2. Pb(NO\(_3\))\(_2\) (remains in solution)
3. Cu(NO\(_3\))\(_2\) (remains in solution)
4. PbSO\(_4\) (potential precipitate)
### Step 5: Solubility Rules
According to solubility rules:
- Most sulfate salts are soluble, but lead(II) sulfate (PbSO\(_4\)) is an exception and is insoluble in water. Therefore, when Pb\(^{2+}\) ions react with SO\(_4^{2-}\) ions, they will form a white precipitate of PbSO\(_4\).
### Step 6: Conclusion
When CuSO\(_4\) is added to Pb(NO\(_3\))\(_2\), a white precipitate of lead(II) sulfate (PbSO\(_4\)) is formed. Thus, the correct answer is **D. a white precipitate would be formed**.
### Explanation of Other Options
- **A. There would be no visible change**: This is incorrect because a visible precipitate (PbSO\(_4\)) is formed.
- **B. A blue precipitate would be formed**: This is incorrect. While CuSO\(_4\) is blue, it does not form a blue precipitate with Pb(NO\(_3\))\(_2\). The precipitate formed is white (PbSO\(_4\)).
- **C. The resulting solution would become colorless**: This is misleading. While the solution may appear less colored due to the formation of a white precipitate, the remaining solution will still contain Cu\(^{2+}\) ions, which impart a blue color to the solution.
### Revision Summary
- When CuSO\(_4\) is mixed with Pb(NO\(_3\))\(_2\), a white precipitate of PbSO\(_4\) forms.
- Lead(II) sulfate (PbSO\(_4\)) is insoluble in water, leading to the formation of a precipitate.
- The other options are incorrect due to the formation of a visible precipitate and the nature of the ions involved.
- Understanding solubility rules is crucial for predicting the outcomes of ionic reactions in solution.