Question 169 of 513
What is the IUPAC name for the following compound? HC\(\equiv\)CCH\(_{3}\)
- A. Acetylene
- B. Methyl acetylene
- C. Butanol
- D. Decanoic acid
Correct Answer:
B
Explanation
The correct option for the IUPAC name of the compound HC≡CCH₃ is **B. Methyl acetylene**. Let's break down the reasoning step-by-step.
### Step-by-Step Explanation
1. **Understanding the Structure**:
- The compound HC≡CCH₃ can be broken down into its components:
- The first carbon (C) is connected to a hydrogen (H) and is part of a triple bond (≡) with the second carbon (C).
- The second carbon (C) is then connected to a third carbon (C) which has three hydrogens (H₃) attached to it.
- This structure can be visualized as:
```
H-C≡C-CH₃
```
- The first carbon (C1) is part of a triple bond with the second carbon (C2), and the second carbon (C2) is connected to a third carbon (C3) which is a methyl group (CH₃).
2. **Identifying the Longest Carbon Chain**:
- The longest continuous carbon chain in this compound consists of three carbon atoms (C1, C2, and C3).
- The presence of a triple bond indicates that this compound is an alkyne.
3. **Naming the Compound**:
- According to IUPAC nomenclature rules, the base name for a three-carbon alkyne is derived from "prop" (for three carbons) and the suffix "-yne" (indicating a triple bond).
- However, since there is a methyl group (CH₃) attached to the terminal carbon (C3), we need to specify this in the name.
- The correct name for this compound is "methyl acetylene" because:
- "Acetylene" refers to the simplest alkyne (C₂H₂), which is ethyne (HC≡CH).
- The methyl group (CH₃) is attached to the terminal carbon of the acetylene structure.
### Why Other Options Are Incorrect
- **A. Acetylene**:
- Acetylene refers specifically to the compound HC≡CH (ethyne), which has only two carbon atoms. Since our compound has three carbon atoms, this option is incorrect.
- **C. Butanol**:
- Butanol is an alcohol with the formula C₄H₉OH. It contains four carbon atoms and a hydroxyl (-OH) group. Our compound does not have a hydroxyl group and has only three carbon atoms, making this option incorrect.
- **D. Decanoic acid**:
- Decanoic acid is a fatty acid with the formula C₁₀H₂₀O₂. It contains ten carbon atoms and a carboxylic acid functional group (-COOH). Our compound does not fit this description, so this option is also incorrect.
### Summary of Key Points
- The compound HC≡CCH₃ has three carbon atoms and a triple bond, classifying it as an alkyne.
- The correct IUPAC name is "methyl acetylene," indicating the presence of a methyl group attached to the acetylene structure.
- Other options are incorrect due to mismatches in the number of carbon atoms or functional groups.
### Revision Summary
- The compound HC≡CCH₃ is named methyl acetylene.
- It consists of three carbon atoms with a triple bond between the first two.
- Acetylene (HC≡CH) has only two carbons, while butanol and decanoic acid have different structures and functional groups.
- Always identify the longest carbon chain and any substituents when naming organic compounds.